Showing posts with label Chemistry JAMB Syllabus. Show all posts
Showing posts with label Chemistry JAMB Syllabus. Show all posts

Tuesday, 11 April 2017

2017/2018 Chemistry JAMB SYLLABUS

CHEMISTRY JAMB Syllabus GENERAL OBJECTIVES



2017/2018 Chemistry JAMB SYLLABUS


The aim of the Unified Tertiary Matriculation Examination (UTME) syllabus in Chemistry is to prepare the candidates for the Board's examination. It is designed to test their achievement of the course objectives, which are to:
(i)apply the basic principles governing scientific methods in new situations;
(ii)interpret scientific data;
(iii)deduce the relationships between chemistry and other sciences;
(iv)apply the knowledge of chemistry to industry and everyday life.



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TOPICS/CONTENTS/NOTES
1. Separation of mixtures and purification of chemical substances
(a)Pure and impure substances
(b)Boiling and melting points.
(c)Elements, compounds and mixtures
(d)Chemical and physical changes.
(e)Separation processes: evaporation, simple and fractional distillation, sublimation, filtration, crystallization, paper and column chromatography, simple and fractional crystallization.

OBJECTIVES
Candidates should be able to:
i.   distinguish between pure and impure substances;
ii.  use boiling and melting points as criteria   for   purity   of chemical substances;
iii. distinguish  between elements, compounds and mixture;
iv. differentiate between chemical and physical changes;
v.  identify the properties of the components of a mixture;
vi. specify the principle involved in each separation method.


TOPICS/CONTENTS/NOTES
2. Chemical combination
Stoichiometry, laws of definite and multiple proportions, law of conservation of matter, Gay Lussac's  law  of   combining volumes, vogadro's law; chemical symbols, formulae, equations and their    uses, relative atomic mass based on l2C=12, the mole concept and Avogadro's number

OBJECTIVES
Candidates should be able to:
(i)   perform simple alculations involving formulae, equations/chemical composition and the mole concept;
(ii) deduce the chemical laws from: given expressions/statements;
(iii) interpret data based on these laws;
(iv) interpret graphical representations related to these laws.



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TOPICS/CONTENTS/NOTES
3. Kinetic theory of matter and Gas Laws
(a) An outline of the kinetic theory of matter, melting, vapourazation and reverse processes; melting and boiling explained in terms of molecular motion and Brownian movement.
(b) The laws of Boyle, Charles, Graham and Dalton (law of partial pressure): combined gas law, molar volume and atomicity of gases.

OBJECTIVES
Candidates should be able to:
(i)   apply the theory to distinguish between solids, liquids and gases;
(ii)  deduce reasons for change of state;
(iii) draw inference based on molecular motion;
(iv) deduce chemical laws form given expressions/ statements;
(v)   interpret graphical representations related to these laws;
(vi) perform simple calculations based on these laws and the relationship Between the vapour density of gases and the relative molecular mass.

TOPICS/CONTENTS/NOTES
4. Atomic structure and bonding
(a)(i)The concept of atoms, molecules and ions, the works of Dalton, Milikan, Rutherford, Mosely,
Thompson and Bohr. Simple hydrogen spectrum, Ionization of gases illustrating the electron as
fundamental particle of matter.
(ii) Atomic structure, electron configuration, atomic number, mass number and isotopes; specific examples should be drawn from elements of atomic number 1 to 20. Shapes of s and p orbitals.
(b)The periodic table and periodicity of  elements,presentation of the periodic table with a view to recognizing families of elements e.g. alkali metals,halogens, the noble gases and transition metals. The variation of the following properties should be noticed: ionization energy, ionic radii, electron affinity and electronegativity.
(c)   Chemical bonding. Electrovalency and covalency, the electron configuration of elements and their tendency to attain the noble gas structure. Hydrogen bonding and metallic bonding as special types of electrovalency andcovalency respectively; coordinate bond as a type of covalent bond as illustrated by compelexes like [Fe(CN)6]3-, [Fe(CN)6]4-, [Cu(NH3)4]2+ and [Ag(NH3)2]+: Van der Waals' forces should be mentioned as a special type of bonding forces.
(d)Shapes of simple molecules; Linear ((H2, 02, C12,HCI and   C02), non-linear   (H20)   and   Tetrahedral; (CR.)
(e)Nuclear Chemistry:
(i) Redioactivity (elementary treatment only)
(ii) Nuclear reactions. Simple equations, uses and applications of natural and artificial Radioactivity.

JAMB SYLLABUS for Chemistry 2017


OBJECTIVES
Candidates should be able to:
(i) distinguish between atom, molecules and ions;
(ii) assess the contributions of these scientists to the development of the atomic structure;
(iii) deduce the number of protons, neutrons and electrons form atomic and mass numbers of an atom;
(iv) apply the rules guiding the arrangement of electrons in an atom;
(v) relate isotopy to mass number;
(vi) perform simple calculations on relative atomic mass
(vii) determine the number of electrons in s and p atomic orbitals.
(viii) relate atomic number to the position of an element on the periodic table;
(ix) relate properties of groups of elements on the periodic table;
(x)  identify reasons for variation in properties across the period.
(xi) Differentiate between the different types of bonding.
(xii) deduce bond types based on electron configurations;
(xiii) relate the nature of bonding to properties of Compounds;
(xiv) apply it in everyday chemistry;
(xv) differentiate between the various, shapes of Molecules
xvi) distinguish between ordinary chemical reaction and nuclear reaction;
(xvii) differentiate between natural and artificial radioactivity;
(xviii) compare the properties of the different types of nuclear radiations;
(xix) compute simple calculations on the half-life of a radioactive materials;
(xx) balance simple nuclear equation;
(xxi) identify the various applications of radioactivity.


TOPICS/CONTENTS/NOTES
5.Air
The usual gaseous constituents - nitrogen, oxygen, water vapour, carbon (IV) oxide and the noble gases (argon and neon), proportion of oxygen in the air e.g. by burning phosphorus or by using alkaline pyrogallol, air as a mixture and some uses of the noble gas.

OBJECTIVES
Candidates should be able to:
(i) deduce reason (s) for the existence of air as a mixture;
(ii) identify the principle involved in the separation of air components;
(iii) deduce reasons for the variation in the composition of air in the environment;
(iv) specify the uses of some of the constituents of air.


TOPICS/CONTENTS/NOTES
6.Water
Composition by volume: Water as a solvent, atmospheric  gases dissolved in water and their biological significance. Water as a product of the combustion of hydrogen. Hard and soft water. Temporary and permanent hardness and methods of softening hard water Purification of town water supplies. Water of crystallization, efflorescence, deliquescence and hygroscopy.
Examples of the substances exhibiting these properties and their uses

OBJECTIVES
Candidates should be able to:
(i) identify the various uses of water
(ii) distinguish between the properties of hard and     soft water;
(iii) determine the causes of hardness;
(iv) identity methods of removal of hardness;
(v) describe the processes involved in the purification of water for town supply;
(vi) distinguish between these phenomena;
(vii) identify the various compounds   that exhibit these phenomena.


TOPICS/CONTENTS/NOTES
7.   Solubility
(a) Unsaturated, saturated And supersaturated solutions. Solubility curves and simple deductions from them, (solubility defined in terms of mole per dm3) and simple calculations.
(b)Solvents for fats, oil and paints and the use of such solvents for the removal of stains.
(c)Suspensions and colloids: Harmdttan haze and pants as examples of suspensions and fog, milk, aerosol spray and rubber solution as examples of colloids.

OBJECTIVES
Candidates should be able to:
(i) distinguish between the different types of solutions;
(ii) interpret solubility curves;
(iii) calculate the amount of solute that can dissolve in a given amount of solven at a given temperature;
(iv) deduce that solubility is temperature-dependent;
(v) classify solvents based on their uses
(vi) differentiate.between a true solution suspension and colloids;
(vii) compare the properties of a true solution and a 'false' solution.
(viii) provide typical examples of suspensions and colloids.


TOPICS/CONTENTS/NOTES
8.Environmental Pollution
(a)Sources and effects of pollutants.
(b)Air pollution:Examples of air pollutants such as H2S, CO, S02, oxides of nitrogen, fluorocarbons and dust
(c)  Water pollution.
Sewage and oil pollution should be known.
(d)  Soil pollution:
Oil spillage, Biodegradable and non-biodegradable pollutants

OBJECTIVES
Candidates should be able to:
(i) identify the different types.of pollution and pollutants;
(ii) classify pollutants as biodegradable and non-biodegradable;
(iii) asses the effects of pollution on the environment;
(iv)  recommend measures for control oi environment pollution.

TOPICS/CONTENTS/NOTES
9.Acids, bases and salts
(a) General characteristics and properties of acids, bases and salts! Acids/base indicators, basicity of acids, normal, acidic,  basic and double salts. An acid defined as a substance whose aqueous solution furnishes H30+ions or as a proton donor. Ethanoic, citric and tartaric acids as examples of naturally occurring organic acids, alums as examples of double slats, preparation of salts by neutralization, precipitation and action of acids on metals. Oxides and trioxocarbonate (IV) salts
(b) Qualitative comparison of the conduct ness of molar solutions of strong and weak acids and bases, relationship between conductance, amount of ions present and their relative mobilities.
(c) pH and pOH scale.pH defined as - log[H30+]
(d) Acid/base titrations.
(e) Hydrolysis of salts: Simple examples such as NH4CI, AICI3, NaC03, CH3COONa to be mentioned

OBJECTIVES
Candidates should be able to:
(i) distinguish between the properties of acids and bases;
(ii) identify the different types of acids and bases;
(iii) differentiate,between-acidity and alkalinity using acid/base
(vi)   relate degree of dissociation to strength of acids and bases;
(vii) relate degree of dissociation to conductance;
(viii) perform simple calculation on pH;
(ix)   identify the appropriate acid-base indicator;
(x)     interpret graphical representation of titration curves;
(xi)    perform simple calculations based on the mole concept;.
(xii)   balance equations for the hydrolysis of salts;
(xiii)  deduce the properties (acidic, basic, neutral) of the resultant solution.


TOPICS/CONTENTS/NOTES
10. Oxidation and reduction
(a)Oxidation in terms of the addition of oxygen or removal of hydrogen.
(b)Reduction as removal of oxygen or addition of hydrogen.
(c)Oxidation and reduction in terms of electron transfer.
(d)Use of oxidation numbers. Oxidation and reduction treated as change in oxidation. number and use of oxidation numbers in balancing simple equations. IUPAC nomenclature o inorganic compounds.
(e)Tests for oxidizing and reducing agents.

OBJECTIVES
Candidates should be able to:
(i)     identify the various forms of expressing oxidation and reduction;
(ii)    classify chemical reactions in terms of oxidation or reduction;
(iii)   balance redox reaction, equations;
(iv)   deduce the oxidation number of chemical species;
(v)    compute the number,.of electron transfer in redox reactions;
(vi) identify the name of redox species using IUPAC nomenclature:
(vii) distinguish between oxidizing and reducing agents in redox reactions.


TOPICS/CONTENTS/NOTES
11.Electrolysis
(a)Electrolytes and non-electrolytes. Faraday's laws of electrolysis.
(b)Electrolysis of dilute H2S04, aqueous CuS04, CuCl2,solution, dilute and concentrated NaCl solutions and fused NaCl and factors affecting discharge of ions at the electrodes.
(c)Uses of electrolysis: Purification of metals e.g. copper and production of elements and compounds e.g. Al, Na, 02, Cl2 andNaOH.
(d)Electrochemical cells: Redox series (K, Na. Ca. Mg.AI, Zn, Fe, Pb, H.Cu.Hg. Au,) Half-cell reactions and Electrode potentials. Simple calculations only.
(e)Corrosion as an electrolytic process, cathodic protection of metals, pairing, electroplating and coating with grease or oil as ways of preventing iron from corrosion.

OBJECTIVES
Candidates should be able to:
(i) identify between electrolytes and non electrolytes;
(ii) perform calculations based on faraday as a mole of electrons.
(iii)  identify suitable electrodes for different electrolytes.
(iv)  specify the chemical reactions a the electrodes;
(v)  determine the products at the electrodes;
(vi)  identify the factors that affect the product of electrolysis;
(vii) specify the different areas of application of electrolysis;
(viii) identify the various electrochemical cells;
(ix) calculate electrode potentials using half- cell reaction equations;
(x) determine the different areas of applications of electrolytic processes;
(xi) apply the methods to protect metals.


TOPICS/CONTENTS/NOTES
12.Energy changes
(a)Energy changes(?H) accompanying physical and chemical changes: dissolution of substances in or reaction with water e.g. Na, NaOH, K, NH4, cl. Endothermic (+?H) and exothermic (-?H) reactions.
(b)Entropy as an order-disorder phenomenon: simple illustration \ like mixing of gases and dissolutioi of salts.
(c)Spontaneity of reactions:
?GO=0 as a criterion for equilibrium, ?GOgreater or less than zero as a criterion for non-spontaneity or spontaneity.

OBJECTIVES
Candidates should be able to:
(i) determine the types of heat changes (?H) in physical and chemical processes;
(ii) interpret graphical representation fo heat changes;
(iii) relate the physical state of a substance to the degree of orderliness;
(iv) determine the conditions for spontaneity of a reaction;
(v)   relate (?H), ?SO and ?GO as driving forces for chemical reactions; (vi)  sole simple problems based on the relationships ?GO= ?HOT?SO)


TOPICS/CONTENTS/NOTES
13. Rates of Chemical Reaction
(a) Elementary treatment of the following factors which can change the rate of a chemical reaction:
(i) Temperature e.g. the reaction between HCI and Na2S203 or Mg and HCI
(ii)   Concentration e.g. the reaction between HCL and Na2S203, HCL and marble and the iodine clock reaction, for gaseous systems, pressure may be used as concentration term.
(iii) Surface area e.g. the reaction between marble and HCI with marble in
(i) powdered form
(ii) lumps of the same mass.
(iv) Catalyst e.g. the decomposition of H202 or KCIO3 in the presence or absence of Mn02
(b)Concentration/time curves.
(c)Activation energy Qualitative treatment of ArrhmuY law and the collision theory, effect of light on some reactions. e.g. halogenation of alkanes

OBJECTIVES
Candidates should be able to:
(i)  identify the factors mat affect the Rates of a chemical reaction;
(ii) determine the effects of these factors on the rate of reactions;
(iii) recommend ways of moderating these effects;
(iv) examine the effect of concentration on the rate of a chemical reaction;
(v) describe how the rate of a chemical reaction is affected by surface area;
(vi) determine the types of catalysts suitable for different reactions.
(vii) interpret reaction rate curves;
(viii) solve simple problems on the rate of reactions;
(x) relate the rate of reaction to the kinetic theory of matter.
(xi) examine the significance of activation energy to chemical reactions.
(xi) deduce the value of activation energy (Ea) from reaction rate curves.


TOPICS/CONTENTS/NOTES
14. Chemical equilibra
Reversible reaction and factors governing the equilibrium position. Dynamic equilibrium. Le Chatelier's principle and equilibrium constant. Simple examples to include action of Steam on iron and N204-2N02. No Calculation will be required.

OBJECTIVES
Candidates should be able to:
(i) identify the factors that affects the position of Equilibrium of a chemical reaction;
(ii) predict the effects of each factor on the position of equilibrium.


TOPICS/CONTENTS/NOTES
15. Non-metals and their compounds
(a) Hydrogen: commercial production from water gas and cracking of petroleum tractions, laboratory preparation, properties, uses and test for hydrogen.
(b) Halogens: Chlorine as a Representative Element of the halogen Laboratory preparation, industrial preparation by electrolysis, properties and uses, e.g. water sterilization, bleaching, manufacture of HC1, plastics and insecticides. Hydrochloric acid preparation and properties. Chlorides and test for chlorides.
(c)Oxygen and Sulphur
(i) Oxygen:
Laboratory preparation, properties and uses. Commercial production from liquid air. Oxides:
Acidic.basic, amphoteric and neutral, trioxygen (ozone) as an allotrope and the   importance of ozone in the atmosphere.
(ii) Sulphur
Uses and allotropes: preparation  of allotropes   is  not expected .  Preparation, properties and uses of sulphur (IV) oxide, the reaction of S02 with alkalis Trioxosulphate (IV) acid and its salts, the effect of acids on salts of trioxosulphate(IV),Tetraoxosulphate (IV) acid. Commercial preparation (contact process only), properties as a dilute acid, an Oxidizing and a dehydrating agent and uses Test for SO42- , Hydrogen sulphide: Preparation and Properties as a weak acid, reducing Agent and precipitating agent. Test for S2-
(d)Nitrogen:
(i) Laboratory preparation
(ii) Production from liquid Air
(iii) Ammonia:
Laboratory and industrial Preparations (Haber Process Only), ammonium salts and their uses, oxidation of ammonia to nitrogen (IV) oxide and trioxonitrate (V) acid test NH4+
(iv)  Trioxonitrate (V) acid: Laboratory preparation from Ammonia; properties and Uses. Trioxonitrate (V) Salt-action of heat and uses. Test for N03
(V) Oxides of nitrogen:
Properties.
The nitrogen cycle.
(e) Carbon:
(i) Allotropes: Uses and properties
(ii) Carbon (IV) oxide- Laboratory preparation, properties and uses. Action of heat on trioxocarbonate (IV) salts and test for CO32-
(iii) Carbon (II) oxide:Laboratory preparation, properties Including its effect on blood; Sources of carbon (II) oxide to Include charcoal, fire and exhaust fumes.
(iv) Coal: Different types, products Obtained form destructive Distillation of wood and coal.
(v) Coke. Gasification and uses.
Manufacture of synthetic gas

OBJECTIVES
Candidates should be able to:
(i) predict reagents for the laboratory and industrial preparation of these gases and their compound.
(ii) identify the properties of the gases and their compounds.
(iii) compare the properties of these gases and their compounds.
(iv) specify the uses of each gas and its compounds;
(v) determine the specific test for each gas its compounds.
(vi) determine specific tests for C1-, S042-, S2-, NH4+, N03-, C032-
(vii)   identify the allotrope oxygen;
(viii) determine the significance of ozone to our Environment.
(ix) identify the allotropes of sulphur and their uses;
(x) specify the commercial preparation of the acid, its properties and uses;
(xi) predicts reagents for the laboratory Preparation for the gas;
(xii) specify the laboratory and industrial Preparation for the gas
(xiii) use Haber process for the industrial Preparation of ammonia;
(xiv) identify reagents.for het laboratory preparation for the acid, its properties and uses;
(xv) examine the relevance of nitrbgen cylce to the environment.
(xvi) identify allotropes fo carbon;
(xvii) predict reagents for the laboratory preparation of C02;
(xviii) specify the properties of the gas and its uses;
(xiv) determine the test for C02;
(xx) determine the reagents for the Laboratory preparation for the gas;
(xxi) examine its effect on human;
(xxii) identify the different forms of coal:
(xxiiii) determine their uses;
(xxiv) specify the uses of coke and synthetic gas.


TOPICS/CONTENTS/NOTES
16. Metals and their compounds

(a) Alkali metals e.g. sodium
(i) Sodium hydroxide:-
Production by electrolysis of Brine, its action on aluminium zinc and lead ions.
Uses including precipitation of metallic hydroxides.
(ii) Sodium trioxo carbonate (IV) and sodium hydrogen trioxocarbonate (IV):
Production by Solvay process, properties and uses, e.g. Na2C03 in the manufacture of glass.
(iii) Sodium chloride: its occurrence in Sea water and uses, the economic Importance fo seawater and the Recovery fo sodium chloride.

(b) Alkaline-earth meals, e.g. calcium; Calcium oxide, calcium hydroxide And calciumtrioxocarbonate (IV); Properties and uses. Preparation of Calcium oxide from sea shells, the Chemical composition for cement And the setting of mortar.
Test For Ca2+.

(c)  Alimimium
Purification of bauxite, Electrolytic extraction properties and uses of aluminium and its compounds. Test for Al3+

(d) Tin
Extraction form tis ores.
Properties and uses.

(e) Metals of the first transition series.
Characteristic properties:
(i) electron configuration
(ii) oxidation states
(iii) complex ion formation
(iv) formation of coloured ions

(f) Iron
Extraction form sulphide and oxide Ores, properties and uses, Different forms of iron and their Properties and advantages of steel over iron.
Test for Fe2+ and Fe3+

(g) Copper
Extraction from sulphide andoxide Ores, properties and uses of copper Salts, preparation and uses of copper (II) tetraoxosulphate   (VI)
Test for Cu2+
(h)    Alloys Steel, stainless steel, brass, bronze, Type-metal, duralumin and soft Solder (constituents and uses only).

OBJECTIVES
Candidates should be able to:
(i) determine the method for extraction suitable For each metal;
(ii) relate the methods of extraction to the Properties for the metals;
(iii) compare the chemical reactivities of the metals;
(iv)  specify the uses of the metals;
(v) determine specific test for metallic ions;
(vi) determine the process for the production of the compounds of these metals;
(vii) compare the chemical reactivities pf the compounds.
(viii)  specify the uses fo these compounds;
(ix) determine the processes for the Preparation of the compounds of the metal;
(x) describe the method of purification of bauxite
(xi) relate the method of extraction to it properties
(xii) specify the uses of tin;
(xiii) identify the general properties of the first transition metals;
(xiv) deduce reasons for the specific properties of the transition metals;
(xv) determine the IUPAC names of simple Transition metal complexes.
(xvi) determine the suitable method of Extraction for the metal;
(xvii)  specify the properties and uses of the metal;
(xviii)identify the appropriate method of extraction for the metal and itscompounds.
(xix) relate the properties of the metal and its compound to their uses.
(xix) specify the constituents and uses of the various alloys mentioned.
(xx)  specify the constituents and uses o: the various alloys mentioned;
(xxi) compare the properties and uses of alloys to pure metals.


TOPICS/CONTENTS/NOTES
17. Organic Compounds
An introduction to the tetravalency of carbon, the general formula, IUP AC nomenclature and the determination of empirical formula of each class of the organic compounds mentioned below.

(a) Aliphatic hydrocarbons (i)Alkanes
Homologous series in relation to physical properties, substitution reaction and a feu examples and uses of halogenated products. Isomerism: structural only (examples on isomerism should not go beyond six carbon atoms).
Petroleum: c o m p o s i t i o n, Fractional distillation and major products; cracking and reforming, Petrochemicals -starting materials of organic syntheses, quality of petrol and meaning ofoctane number.
(ii) Alkenes
Isomerism: structural and geometric Isomerism, additional and Polymerization reactions, polythene And synthetic rubber as examples of Products of polymerization and its use In vulcanization.
(iii) Alkynes
Ethyne - production form action of Water on carbides, simple reactions and Properties of ethyne.

(b) Aromatic hydrocarbons e.g. benzene - Structure, properties and uses.

(c)   Alkanols
Primary, secondary, tertiary -production Of ethanol by fermentation and form Petroleum by¬products. Local examples of fermentation and distillation, e.g. Gin from palm wine and other local Sources and glycerol as a polyhydric  alkanol. Reactions of OH group - oxidation as a distinguishing test between primary,. Secondary and tertiary alkanols.

(d)Alakanals and alkanones. Chemical test to distinguish between Alakanals and alkanones.

(e)Alkanoic acids.
Chemical reactions; neutralization and Esterification, ethanedioic (oxalic) acid As an example of a dicarboxylic acid And benzene carboxylic acid as an example of an aromatic acid.

(f)Alkanoates
Formation from alkanoic acids and Alkanols - fats and oils as alkanoates Saponification:
Production of soap and margarine from Alkanoates and distinction between Detergents and soaps.

(g) Amines (Alkanamines) Primary, Secondary, tertiary

(h) Carbohydrates
Classification - mono, di and polysaccharides, composition, chemical Tests for simple sugars and reaction With concentrated tetraoxosulphate (VI) Acid. Hydrolysis of Complex sugar e.g. cellulose form cotton and starch fron cassava, the uses of sugar and starch in athe production of alcoholic beverage, pharmaceuticast and textiles.
(i) Giant molecules e.g. proteins, enzymes, Natural rubbers and polymers.

OBJECTIVES
Candidates should be able to:
(i) derive the name of organic compounds form their general formulae;
(ii) relate the name of a compound to its structure
(iii) relate the tetravalency of carbon to its ability to form chains of compound (catenation);
(iv) classify compounds according to their Functional groups;
(v)  derive empirical formula and molecular formula, given data;
(vi) relate structure/functional groups tc specific Properties;
(vii) derive various isomeric form from given formula;
(viii) distinguish between the different types of Isomerism;
(ix) classify the various types of hydrocarbon;.
(x)  distinguish each class of hydrocarbon by their properties
(xi)  specify the uses of various hydrocarbons;
(xii) identify crude oil as a complex mixture of hydrocarbon;
(xiii) relate the fractions of hydrpcarboi to their Properties and sues;
(xiv) relate transformation process to quality Improvement of the fractions. xv) distinguishing between various polymerization processes.
(xvi) distinguishing between aliphatic and Aromatic hydrocarbons;
(xvii) relate the properties of benzene to its structure
(xviii)compare the various classes of alkanols;
(xix)   determine the processes involved in ethanol Production;
(xx)    examine the importance of ethanol as an Alternative energy provider.
(xxi)    differentiate between alkanals and alkanones;
(xxii)  compare the various classes of alkanoic acid;
(xxiii) identify natural sources of alkanoates;
(xxiv) specify the sues of alkanoates;
(xxv)  distinguish between detergent and soap;
(xxvi) compare the various classes of alkanamine;
(xxvii) identify the natural sources of carbohydrates and giant molecules;
(xxviii)compare the various classes of carbohydrates;
(xxix) infer the product of hydrolysis of carbohydrates;
(xxx)  determine the uses of carbohydrates;
(xxxi) reale giant molecuales to their uses

RECOMMENDED TEXTS
Ababio, O.Y. (2005) New School Chenistiy for Senior Secodnary Schools, (Third Edition), Onitsha: Africana FIRST Publishers Limited
Bajah, S.T. Teibi, B.O. Onwu, G and Obikwere, A. (1999) Senior Secodnary Chemistry, Book 1, Lagos: Longman
Bajah, S.T. Teibo, B.O. Onwu, G and Onikwere, A. 2000) Senior Secondary Chemsitry, Book 2 and 3, Lagos: Longman
Ohia, G.N.C. Adewoyin, F.A. and Akpan, B.B. (1997) Exam Focus Chenistiy for WASSCE & JME: Ibadan: University Press Pic
STAN (1987) Chemsitry for Senor Seconary Schools, Ibadan: Heinemann
Sylvesta: O.O. (2004) A Comprehesnive Practical Chemistry for Senior Secondary Schools, Ibadan: Evans
Uche, I.O. Adenuga, I J. and Iwuagwu, S.L. (2003) Countdown to WASSCE/SSpE, NECO, JME Chemsitry, Ibadan: Evans

Tuesday, 31 January 2017

2017/2018 Chemistry JAMB Syllabus and Recommended Textbooks

Chemistry JAMB Syllabus 2017 and Recommended Textbooks 
Chemistry JAMB Syllabus




Text your name and email for activation keys ➡ 09034039101

Text your name and email for activation keys ➡ 09034039101

CHEMISTRY GENERAL OBJECTIVES

The aim of this 2017/2018 Unified Tertiary Matriculation Examination (UTME) syllabus in Chemistry is to prepare the candidates for the Board's examination. It is designed to test their achievement of the course objectives, which are to:

(i) understand the basic principles and concepts in chemistry;
(ii) interpret scientific data relating to chemistry;
(iii) deduce the relationships between chemistry and other sciences;
(iv) apply the knowledge of chemistry to industry and everyday life.

TOPICS/CONTENTS/NOTES OBJECTIVES

1. Separation of mixtures and purification of chemical substances


(a) Pure and impure substances
(b) Boiling and melting points.
(c) Elements, compounds and mixtures
(d) Chemical and physical changes.
(e) Separation processes:
evaporation, simple and fractional distillation, sublimation, filtration, crystallization, paper and column chromatography, simple and fractional crystallization, magnetization, decantation.
Candidates should be able to:
(i) distinguish between pure and impure substances;
(ii) use boiling and melting points as criteria for purity of chemical substances;
(iii) distinguish between elements, compounds and mixture;
(iv) differentiate between chemical and physical changes;
(v) identify the properties of the components of a mixture;
(vi) specify the principle involved in each separation method.
(vii) apply the basic principle of separation processes in everyday life.

2. Chemical combination


Stoichiometry, laws of definite and multiple proportions, law of conservation of matter, Gay Lussac's law of combining volumes, Avogadro's law; chemical symbols, formulae, equations and their uses, relative atomic mass
based on 12C=12, the mole concept and Avogadro's number.
Candidates should be able to:
(i) perform simple calculations involving formulae, equations/chemical composition and the mole concept;
(ii) deduce the chemical laws from given expressions/statements/data;
(iii) interpret graphical representations related
to these laws;
(iv) deduce the stoichiometry of chemical reactions.

3. Kinetic theory of matter and Gas Laws


(a) An outline of the kinetic theory of matter;
(i) melting,
(ii) vapourization
(iii) boiling
(iv) freezing
(v) condensation
in terms of molecular motion and Brownian movement.
(b)(i) The laws of Boyle, Charles, Graham and Dalton (law of partial pressure); combined gas law, molar volume and atomicity of gases.
(ii) The ideal gas equation (PV = nRT).
(iii) The relationship between vapour density of gases and the relative molecular mass.
Candidates should be able to:
(i) apply the theory to distinguish between solids, liquids and gases;
(ii) deduce reasons for change of state;
(iii) draw inferences based on molecular motion;
(iv) deduce gas laws from given expressions/ statements;
(v) interpret graphical representations related to these laws;
(vi) perform simple calculations based on these laws, equations and relationships

4. Atomic structure and bonding


(a) (i)The concept of atoms, molecules and ions, the works of Dalton, Millikan, Rutherford, Moseley, Thompson and Bohr.
(ii) Atomic structure, electron configuration, atomic number, mass number and isotopes; specific examples should be drawn from elements of atomic number 1 to 20.
(iii) Shapes of s and p orbitals.
(b) The periodic table and periodicity of elements, presentation of the periodic table with a view to recognizing families of elements e.g. alkali metals, halogens, the noble gases and transition metals. The variation of the following properties: ionization energy, ionic radii, electron affinity and electronegativity.
(c) Chemical bonding.
Electrovalency and covalency, the electron configuration of elements and their tendency to attain the noble gas structure. Hydrogen bonding and metallic bonding as special types of electrovalency and covalency respectively; coordinate bond as a type of covalent bond as illustrated by complexes like [Fe(CN)6]3-, [Fe(CN)6]4-, [Cu(NH3)4]2+ and [Ag(NH3)2]+; van der Waals' forces should be mentioned as a special type of bonding forces.
(d) Shapes of simple molecules: linear ((H2, O2, C12,HCl and CO2), non-linear (H2O) and tetrahedral; (CH4) and pyramidal (NH3).
(e) Nuclear Chemistry:
(i) Radioactivity - Types and properties of
radiations
(ii) Nuclear reactions. Simple equations,
uses and applications of natural and
artificial radioactivity.
Candidates should be able to:
(i) distinguish between atoms, molecules and ions;
(ii) identify the contributions of these scientists to
the development of the atomic structure;
(iii) deduce the number of protons, neutrons and
electrons from atomic and mass numbers of
an atom;
(iv) apply the rules guiding the arrangement of
electrons in an atom;
(v) identity common elements exhibiting isotopy;
(vi) relate isotopy to mass number;
(vii) perform simple calculations relating to isotopy;
(viii) differentiate between the shapes of the orbitals;
(ix) determine the number of electrons in s and
p atomic orbitals;
(x) relate atomic number to the position of an
element on the periodic table;
(xi) relate properties of groups of elements on the periodic table;
(xii) identify reasons for variation in properties
across the period and down the groups.
(xiii) differentiate between the different types
of bonding.
(xiv) deduce bond types based on electron
configurations;
(xv) relate the nature of bonding to properties
of compounds;
(xvi) differentiate between the various shapes
of molecules
xvii) distinguish between ordinary chemical
reaction and nuclear reaction;
(xviii) differentiate between natural and
artificial radioactivity;
(xix) compare the properties of the different
types of nuclear radiations;
(xx) compute simple calculations on the
half-life of a radioactive material;
(xxi) balance simple nuclear equation;
(xxii) identify the various applications of
radioactivity.

5. Air


(a) The natural gaseous constituents and their proportion in the air.
- nitrogen, oxygen, water vapour, carbon (IV) oxide and the noble gases (argon and neon).
(b) Air as a mixture and some uses of the noble gas.
Candidates should be able to:
(i) deduce reason (s) for the existence of
air as a mixture;
(ii) identify the principle involved in the
separation of air components;
(iii) deduce reasons for the variation in the
composition of air in the environment;
(iv) specify the uses of some of the
constituents of air.

6. Water


(a) Water as a product of the combustion of hydrogen and its composition by volume.
(b) Water as a solvent, atmospheric gases dissolved in water and their biological significance.
(c) Hard and soft water:
Temporary and permanent
hardness and methods of softening
hard water.
(d) Treatment of water for town supply.
(e) Water of crystallization, efflorescence,
deliquescence and hygroscopy. Examples of the substances exhibiting these properties and their uses.
Candidates should be able to:
(i) identify the various uses of water;
(ii) identity the effects of dissolved atmospheric
gases in water;
(iii) distinguish between the properties of hard and
soft water;
(iv) determine the causes of hardness;
(v) identify methods of removal of hardness;
(vi) describe the processes involved in the
treatment of water for town supply;
(vii) distinguish between these phenomena;
(viii) identify the various compounds that exhibit
these phenomena.

7. Solubility


(a) Unsaturated, saturated and supersaturated solutions. Solubility curves and simple deductions from them, (solubility defined in terms of mole per dm3) and simple calculations.
(b) Solvents for fats, oil and paints
and the use of such solvents
for the removal of stains.
(c) False solution (Suspensions and colloids):
Properties and examples.
Harmattan haze and water paints as examples
of suspensions and fog, milk, aerosol spray,
emulsion paints and rubber solution as
examples of colloids.
Candidates should be able to:
(i) distinguish between the different types of
solutions;
(ii) interpret solubility curves;
(iii) calculate the amount of solute that can
dissolve in a given amount of solvent at a
given temperature;
(iv) deduce that solubility is temperature-dependent;
(v) relate nature of solvents to their uses;
(vi) differentiate among true solution,
suspension and colloids;
(vii) compare the properties of a true solution
and a �false' solution.
(viii) provide typical examples of suspensions
and colloids.

8. Environmental Pollution


(a) Sources and effects of pollutants.
(b) Air pollution:
Examples of air pollutants such as
H2S, CO, SO2, oxides of nitrogen,
chlorofluorocarbons and dust.
(c) Water pollution
Sewage and oil pollution should be
known.
(d) Soil pollution:
Oil spillage, Biodegradable and
non-biodegradable pollutants.
Candidates should be able to:
(i) identify the different types of pollution and
pollutants;
(ii) specify different sources of pollutants
(iii) classify pollutants as biodegradable and
non-biodegradable;
(iv) specify the effects of pollution on the
environment;
(v) identify measures for control of
environmental pollution.

9. Acids, bases and salts


(a) General characteristics and properties of acids, bases and salts. Acids/base indicators, basicity of acids; normal, acidic, basic and
double salts. An acid defined as a substance whose aqueous solution furnishes H3O+ions or as a proton donor. Ethanoic, citric and tartaric acids as examples of naturally occurring organic acids, alums as examples
of double salts, preparation of salts by neutralization, precipitation and action of acids on metals. Oxides and trioxocarbonate (IV) salts
(b) Qualitative comparison of the
conductances of molar solutions of
strong and weak acids and bases,
relationship between conductance and
amount of ions present.
(c) pH and pOH scale; Simple calculations
(d) Acid/base titrations.
(e) Hydrolysis of salts: Principle
Simple examples such as
NH4Cl, AlCl3, Na2CO3 and CH3COONa
Candidates should be able to:
(i) distinguish between the properties of
acids and bases;
(ii) identify the different types of acids
and bases;
(iii) determine the basicity of acids;
(iv) differentiate between acidity and
alkalinity using acid/base indicators;
(v) identify the various methods of
preparation of salts;
(vi) classify different types of salts;
(vii) relate degree of dissociation to strength
of acids and bases;
(viii) relate degree of dissociation to
conductance;
(ix) perform simple calculations on pH and pOH;
(x) identify the appropriate acid-base
indicator;
(xi) interpret graphical representation of
titration curves;
(xii) perform simple calculations based on
the mole concept;
(xiii) balance equations for the hydrolysis
of salts;
(xiv) deduce the properties (acidic, basic,
neutral) of the resultant solution.

10. Oxidation and reduction


(a) Oxidation in terms of the addition of oxygen or removal of hydrogen.
(b) Reduction as removal of oxygen or
addition of hydrogen.
(c) Oxidation and reduction in terms of electron transfer.
(d) Use of oxidation numbers. Oxidation and reduction treated as change in oxidation number and use of oxidation numbers in balancing simple equations.
(e) IUPAC nomenclature of inorganic compounds using oxidation number.
(f) Tests for oxidizing and reducing agents.
Candidates should be able to:
(i) identify the various forms of expressing
oxidation and reduction;
(ii) classify chemical reactions in terms of
oxidation or reduction;
(iii) balance redox reaction equations;
(iv) deduce the oxidation number of chemical
species;
(v) compute the number of electron transfer
in redox reactions;
(vi) identify the name of redox species in a reaction
(vii) distinguish between oxidizing and reducing
agents in redox reactions.
(viii) apply oxidation number in naming inorganic compounds
(ix) relate reagents to their oxidizing and reducing abilities.

11. Electrolysis


(a) Electrolytes and non-electrolytes.
Faraday's laws of electrolysis.
(b) (i) Electrolysis of dilute H2SO4, aqueous
CuSO4, CuC12 solution, dilute and concentrated NaC1 solutions and fused NaC1
(ii) Factors affecting discharge of ions at the electrodes.
(c) Uses of electrolysis:
Purification of metals e.g. copper and
production of elements and compounds
(Al, Na, O2, Cl2 and NaOH).
(d) Electrochemical cells:
Redox series (K, Ca, Na, Mg, Al, Zn, Fe, Sn, Pb, H, Cu, Hg, Ag, Au,)
half-cell reactions and electrode potentials. (Simple calculations only).
(e) Corrosion as an electrolytic process,
cathodic protection of metals,
painting, electroplating and coating
with grease or oil as ways of
preventing iron from corrosion.
Candidates should be able to:
(i) distinguish between electrolytes and non-
electrolytes;
(ii) perform calculations based on faraday as a
mole of electrons.
(iii) identify suitable electrodes for different
electrolytes.
(iv) specify the chemical reactions at the
electrodes;
(v) determine the products at the electrodes;
(vi) identify the factors that affect the products
of electrolysis;
(vii) specify the different areas of application of
electrolysis;
(viii) identify the various electrochemical cells;
(ix) calculate electrode potentials using half-
cell reaction equations;
(x) determine the different areas of
application of electrolytic processes;
(xi) identify methods used in protecting metals.

12. Energy changes


(a) Energy changes(Δ
H) accompanying physical
and chemical changes:
dissolution of substances in/or
reaction with water e.g. Na, NaOH,
K, NH4Cl. Endothermic (+ΔH) and exothermic (-ΔH) reactions.
(b) Entropy as an order-disorder
phenomenon: simple illustrations
like mixing of gases and dissolution
of salts.
(c) Spontaneity of reactions:
ΔGθ = 0 as a criterion for equilibrium, Δ
G
greater or less than zero as a criterion for
non-spontaneity or spontaneity respectively.
Candidates should be able to:
(i) determine the types of heat changes
(Δ
H) in physical and chemical processes;
(ii) interpret graphical representations of heat
changes;
(iii) relate the physical state of a substance
to the degree of orderliness;
(iv) determine the conditions for spontaneity
of a reaction ;
(v) relate ΔHθ, ΔSθ and ΔGθ as the driving
forces for chemical reactions;
(vi) solve simple problems based on the
relationships ΔGθ= ΔHθ -TΔSθ

13. Rates of Chemical Reaction


(a) Elementary treatment of the following factors which can change the rate of a chemical reaction:
(i) Temperature e.g. the reaction between HCl and Na2S2O3 or Mg and HCl
(ii) Concentration e.g. the reaction between HCl and Na2S2O3, HCl and marble and the iodine clock reaction, for gaseous systems, pressure may be used as concentration term.
(iii) Surface area e.g. the reaction
between marble and HCl with
marble in
(i) powdered form
(ii) lumps of the same mass.
(iv) Catalyst e.g. the decomposition
of H2O2 or KClO3 in the
presence or absence of MnO2
(b) Reaction rate curves.
(c) Activation energy
Qualitative treatment of Arrhenius' law and
the collision theory, effect of light on some
reactions. e.g. halogenation of alkanes
Candidates should be able to:
(i) identify the factors that affect the rates of a chemical reaction;
(ii) determine the effects of temperature on
the rate of reactions;
(iii) examine the effect of concentration/pressure on
the rate of a chemical reaction;
(iv) describe how the rate of a chemical reaction is
affected by surface area;
(v) determine the types of catalysts suitable for different reactions and their effects;
(vi) determine ways of moderating these effects in chemical reactions.
(vii) interpret reaction rate curves;
(viii) solve simple problems on the rate of reactions;
(ix) relate the rate of reaction to the kinetic theory of matter.
(x) examine the significance of activation energy to chemical reactions.
(xi) deduce the value of activation energy (Ea) from reaction rate curves.

14. Chemical equilibra


Reversible reactions and factors governing
the equilibrium position. Dynamic
equilibrium. Le Chatelier's principle and equilibrium constant. Simple examples to
include action of steam on iron and N2O4 2NO2.
No calculation will be required.
Candidates should be able to:
(i) identify the factors that affects the position
of equilibrium of a chemical reaction;
(ii) predict the effects of each factor on the position
of equilibrium;
(iii) determine the effects of these factors on
equilibrium constant.

15. Non-metals and their compounds


(a) Hydrogen: commercial production from
water gas and cracking of petroleum
fractions, laboratory preparation,
properties, uses and test for hydrogen.
(b) Halogens: Chlorine as a representative
element of the halogen. Laboratory preparation, industrial preparation by electrolysis, properties and uses, e.g. water sterilization, bleaching, manufacture of HCl, plastics and insecticides.
Hydrogen chloride and Hydrochloric acid: Preparation and properties. Chlorides and test for chlorides.
(c) Oxygen and Sulphur
(i) Oxygen:
Laboratory preparation, properties and uses. Commercial production from liquid air. Oxides: Acidic,basic, amphoteric and neutral, trioxygen (ozone) as an allotrope and the importance of ozone in the atmosphere.
(ii) Sulphur:
Uses and allotropes:
preparation of allotropes is not expected . Preparation, properties and uses of sulphur(IV) oxide, the reaction of SO2 with alkalis. Trioxosulphate (IV) acid and its salts, the effect of acids on salts of trioxosulphate(IV), Tetraoxosulphate(VI) acid: Commercial preparation (contact process only), properties as a dilute acid, an oxidizing and a dehydrating agent and uses. Test for SO42-.
Hydrogen sulphide: Preparation and properties as a weak acid, reducing agent and precipitating agent. Test for S2-
(d) Nitrogen:
(i) Laboratory preparation
(ii) Production from liquid air
(iii) Ammonia:
Laboratory and industrial
preparations (Haber Process only),
properties and uses, ammonium salts
and their uses, oxidation of
ammonia to nitrogen (IV)
oxide and trioxonitrate (V)
acid.
Test for NH4+
(iv) Trioxonitrate (V) acid:
Laboratory preparation
from ammonia;
properties and uses. Trioxonitrate (V) salt-
action of heat and uses. Test for NO3-
(v) Oxides of nitrogen:
Properties.
The nitrogen cycle.
(e) Carbon:
(i) Allotropes: Uses and
properties
(ii) Carbon(IV) oxide-
Laboratory preparation, properties
and uses. Action of heat on
trioxocarbonate (IV) salts and test for
CO32-
(iii) Carbon(II) oxide:
Laboratory preparation, properties
including its effect on blood;
sources of carbon (II) oxide to
include charcoal, fire and exhaust
fumes.
(iv) Coal: Different types, products
obtained from destructive
distillation of wood and coal.
(v) Coke: Gasification and uses.
Manufacture of synthetic gas and
uses.
Candidates should be able to:
(i) predict reagents for the laboratory and
industrial preparation of these gases and
their compounds.
(ii) identify the properties of the gases and their
compounds.
(iii) compare the properties of these gases and
their compounds.
(iv) specify the uses of each gas and its
compounds;
(v) determine the specific test for each gas and its
compounds.
(vi) determine specific tests for Cl-, SO42-, SO32-,
S2-, NH4+, NO3-, CO32-, HCO?3
(vii) predict the reagents for preparation,
properties and uses HCl(g) and HCl(aq);
(viii) identify the allotropes of oxygen;
(ix) determine the significance of ozone to
our environment.
(x) classify the oxides of oxygen and their
properties
(xi) identify the allotropes of sulphur and their
uses;
(xii) predict the reagents for preparation, properties
and uses of SO2 and H2S;
(xiii) specify the preparations of H2SO4 and H2SO3,
their properties and uses.
(xiv) specify the laboratory and industrial
preparation of NH3;
(xv) identify the properties and uses of NH3;
(xvi) identify reagents for the laboratory
preparation of HNO3, its properties and
uses;
(xvii) specify the properties of N2O, NO, NO2 gases.
(xviii) examine the relevance of nitrogen cycle
to the environment.
(xix) identify allotropes of carbon;
(xx) predict reagents for the laboratory
preparation of CO2;
(xxi) specify the properties of CO2 and its
uses;
(xxii) determine the reagents for the
laboratory preparation of CO;
(xxiii) predict the effects of CO on human;
(xxiv) identify the different forms of coal:
(xxv) determine their uses;
(xxvi) specify the products of the destructive distillation of wood and coal;
(xxvii) specify the uses of coke and synthetic gas.

16. Metals and their compounds


(a) General properties of metals
(b) Alkali metals e.g. sodium
(i) Sodium hydroxide:-
Production by electrolysis of
brine, its action on aluminium, zinc and lead ions.
Uses including precipitation of
metallic hydroxides.
(ii) Sodium trioxocarbonate (IV)
and sodium hydrogen trioxocarbonate (IV): Production by Solvay process, properties and uses, e.g.
Na2CO3 in the manufacture of glass.
(iii) Sodium chloride: its occurrence in
sea water and uses, the economic
importance of sea water and the
recovery of sodium chloride.
(c) Alkaline-earth metals, e.g. calcium;
calcium oxide, calcium hydroxide
and calcium trioxocarbonate (IV);
Properties and uses. Preparation of calcium oxide from sea shells, the
chemical composition of cement
and the setting of mortar. Test for Ca2+.
(d) Aluminium
Purification of bauxite, electrolytic
extraction, properties and uses of aluminium and its compounds. Test for A13+
(e) Tin
Extraction from its ores.
Properties and uses.
(f) Metals of the first transition series.
Characteristic properties:
(i) electron configuration
(ii) oxidation states
(iii) complex ion formation
(iv) formation of coloured ions
(v) catalysis
(g) Iron
Extraction from sulphide and oxide
ores, properties and uses, different forms
of iron and their properties and
advantages of steel over iron.
Test for Fe2+ and Fe3+
(h) Copper
Extraction from sulphide and oxide
ores, properties and uses of copper.
Preparation and uses of copper( II )
tetraoxosulphate(VI). Test for Cu2+
(i) Alloy
Steel, stainless steel, brass, bronze, type- metal, duralumin, soft solder,
permallory and alnico (constituents and
uses only).
Candidates should be able to:
(i) specify the general properties of metals;
(ii) determine the method of extraction suitable
for each metal;
(iii) relate the methods of extraction to the
properties for the metals;
(iv) compare the chemical reactivities of the metals;
(v) specify the uses of the metals;
(vi) determine specific test for metallic ions;
(vii) determine the process for the production
of the compounds of these metals;
(viii) compare the chemical reactivities of the
compounds;
(ix) specify the uses of these compounds;
(x) specify the chemical composition of cement.
(xi) describe the method of purification of bauxite;
(xii) specify the ores of tin;
(xiii) relate the method of extraction to its properties;
(xiv) specify the uses of tin;
(xv) identify the general properties of the first
transition metals;
(xvi) deduce reasons for the specific properties
of the transition metals;
(xvii) determine the IUPAC names of simple
transition metal complexes
(xviii) determine the suitable method of
extraction of iron;
(xix) specify the properties and uses of iron;
(xx) identify the different forms of iron, their compositions, properties and uses.
(xxi) identify the appropriate method of
extraction of copper from its compounds;
(xxii) relate the properties of copper and its
compound to their uses.
(xxiii) specify the method for the preparation of
CuSO4;
(xxiv) specify the constituents and uses of the
various alloys mentioned.
(xxv) compare the properties and uses of alloys
to pure metals.

17. Organic Compounds


An introduction to the tetravalency of
carbon, the general formula, IUPAC
nomenclature and the determination of
empirical formula of each class of the
organic compounds mentioned below.
(a) Aliphatic hydrocarbons
(i) Alkanes
Homologous series in relation
to physical properties,
substitution reaction and a few
examples and uses of halogenated
products. Isomerism: structural
only (examples on isomerism should
not go beyond six carbon atoms).
Petroleum: composition, fractional distillation and major products; cracking and reforming, Petrochemicals - starting materials of organic syntheses, quality of petrol and meaning of octane number.
(ii) Alkenes
Isomerism: structural and geometric
isomerism, additional and
polymerization reactions, polythene
and synthetic rubber as examples of
products of polymerization and its use
in vulcanization.
(iii) Alkynes
Ethyne - production from action of
water on carbides, simple reactions and
properties of ethyne.
(b) Aromatic hydrocarbons e.g. benzene -
structure, properties and uses.
(c) Alkanols
Primary, secondary, tertiary - production
of ethanol by fermentation and from
petroleum by-products. Local examples
of fermentation and distillation, e.g.
gin from palm wine and other local
sources and glycerol as a polyhydric
alkanol.
Reactions of OH group - oxidation as a distinguishing test among primary, secondary
and tertiary alkanols (Lucas test).
(d) Alkanals and alkanones.
Chemical test to distinguish between
alkanals and alkanones.
(e) Alkanoic acids.
Chemical reactions; neutralization and
esterification, ethanedioic (oxalic) acid
as an example of a dicarboxylic acid
and benzene carboxylic acid as an
example of an aromatic acid.
(f) Alkanoates
Formation from alkanoic acids and
alkanols - fats and oils as alkanoates.
Saponification:
Production of soap and margarine from
alkanoates and distinction between
detergents and soaps.
(g) Amines (Alkanamines) Primary, Secondary,
and tertiary
(h) Carbohydrates
Classification - mono-, di- and polysaccharides; composition, chemical tests for simple sugars and reaction with concentrated tetraoxosulphate (VI) acid. Hydrolysis of complex sugars e.g. cellulose from cotton and starch from cassava, the uses of sugar and starch in the production of alcoholic beverages, pharmaceuticals and textiles.
(i) Proteins:
Primary structures, hydrolysis and tests (Ninhydrin, Biuret, Millon's and xanthoproteic)
Enzymes and their functions.
(j) Polymers:
Natural and synthetic rubber; addition and condensation polymerization.
- Methods of preparation, examples and uses.
Thermoplastic and thermosetting plastics.
Candidates should be able to:
(i) derive the name of organic compounds from
their general formulae;
(ii) relate the name of a compound to its structure
(iii) relate the tetravalency of carbon to its ability
to form chains of compound (catenation);
(iv) classify compounds according to their
functional groups;
(v) derive empirical formula and molecular
formula, from given data;
(vi) relate structure/functional groups to specific
properties;
(vii) derive various isomeric forms from a given
formula;
(viii) distinguish between the different types of
isomerism;
(ix) classify the various types of hydrocarbons;
(x) distinguish each class of hydrocarbons by their properties;
(xi) specify the uses of various hydrocarbons;
(xii) identify crude oil as a complex mixture
of hydrocarbons;
(xiii) relate the fractions of hydrocarbons to their
properties and uses;
(xiv) relate transformation processes to quality
improvement of the fractions;
(xv) distinguish between various polymerization
processes;
(xvi) specify the process involved in vulcanization;
(xvii) specify chemical test for terminal alkynes
(xviii) distinguish between aliphatic and aromatic
hydrocarbons;
(xix) relate the properties of benzene to its structure
(xx) compare the various classes of alkanols;
(xxi) determine the processes involved in ethanol
production;
(xxii) examine the importance of ethanol as an
alternative energy provider;
(xxiii) distinguish the various classes of alkanols;
(xxiv) differentiate between alkanals and alkanones;
(xxv) compare the various types of alkanoic acids;
(xxvi) identify natural sources of alkanoates;
(xxvii) specify the methods for the production of
soap, detergent and margarine.
(xxviii) distinguish between detergent and soap;
(xxix) compare the various classes of alkanamine;
(xxx) identify the natural sources of
carbohydrates;
(xxxi) compare the various classes of
carbohydrates;
(xxxii) infer the products of hydrolysis and
dehydration of carbohydrates;
(xxxiii) determine the uses of carbohydrates;
(xxxiv) specify the tests for simple sugars;
(xxxv) identify the basic structure of proteins;
(xxxvi) specify the methods and products of
hydrolysis;
(xxxvii) specify the various tests for proteins;
(xxxviii) distinguish between natural and synthetic
polymers;
(xxxix) differentiate between addition and
condensation polymerization processes;
(xl) classify natural and commercial polymers
and their uses;
(xli) distinguish between thermoplastics and
thermosetting plastics.

18. Chemistry and Industry


Chemical industries: Types, raw materials and
relevancies; Biotechnology.
Candidates should be able to :
(i) classify chemical industries interms of products;
(ii) identify raw materials for each industry;
(iii) distinguish between fine and heavy
chemicals;
(iv) enumerate the relevance of each of these
industries;
(v) relate industrial processes to biotechnology.
 

RECOMMENDED TEXTS


1. New School Chemistry for Senior Secondary Schools, Ababio, O. Y. (2009), (Fourth edition), Onitsha: Africana FIRST Publishers Limited.

2. Senior Secondary Chemistry, Bajah, S.T.; Teibo, B. O., Onwu, G.; and Obikwere, A. Book 1 (1999), Books 2 and 3 (2000). Lagos: Longman.

3. Understanding Chemistry for Schools and Colleges, Ojokuku, G. O. (2012, Revised Edition), Zaria: Press-On Chemresources.

4. Essential: Chemistry for Senior Secondary Schools, (2008), 2nd Edition, I. A. Odesina, Lagos: Tonad Publishers Limited.

5. Countdown to WASSCE/SSCE, NECO, JME Chemistry, Uche, I. O.; Adenuga, I. J. and Iwuagwu, S. L. (2003). Ibadan: Evans.

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